[
  {
    "id": "row-1",
    "claim": "PFAS-free two-phase immersion coolant broad genus",
    "figure": "Claimed funnel 7.9M→1.87M→427k→5371→931; dielectric 1.5–1.9; 27 viable pairs",
    "reproduce_command": null,
    "receipt_paths": [],
    "negative_control": "The siloxane screen exits 1 when its required sibling Pareto CSV is absent.",
    "basis": "estimate: imported/3prok/00_TOP3_IDEAS_RANKED.md and cooling-fluid-10/docs/PFAS_FREE_COOLING_OPTIMUM.md. Original funnel inputs/scripts are not available here. The pair screen requires an absent external CSV. Electronic polarizability agreement does not establish static liquid permittivity. The claimed $12.5B supply gap misuses a settlement amount.",
    "source": "gpt-6-astra read-only audit of this repository, 2026-09-07 (C1)"
  },
  {
    "id": "row-2",
    "claim": "Pentane+GBL 80:20 canonical screening lead",
    "figure": "FoM4 4.06×; delta-sigma 27.57 mN/m; epsilon estimate 8.28; viscosity estimate 0.319 mPa·s",
    "reproduce_command": "python3 -B -c 'import runpy;m=runpy.run_path(\"cooling-fluid-10/scripts/extend_fom_top10.py\");p=\"GBL\";b=m[\"blend_properties\"](\"Pentane\",p);print(m[\"fom4\"](m[\"load_canonical_sigma\"]()[\"Pentane+\"+p][\"sigma\"],p,b));print(\"epsilon\",round(b[\"epsilon\"],2),\"mu\",round(b[\"mu_mPas\"],3))'",
    "receipt_paths": [
      "cooling-fluid-10/data/processed/corrected_fom_nist.json"
    ],
    "negative_control": "Shared FoM input-perturbation control passes; constant-sigma regression control returns zero slope.",
    "basis": "computational estimate: canonical sigma plus literature-property mixing. The historical seven-member pool and temperature fit also reproduce as detailed below. Neither establishes miscibility, actual self-pumping or direct-immersion qualification.",
    "source": "gpt-6-astra read-only audit of this repository, 2026-09-07 (C1)"
  },
  {
    "id": "row-3",
    "claim": "Pentane+DMC 80:20 low-permittivity screening candidate",
    "figure": "epsilon estimate 2.05; FoM4 3.50×; delta-sigma 11.25 mN/m",
    "reproduce_command": "python3 -B -c 'import runpy;m=runpy.run_path(\"cooling-fluid-10/scripts/extend_fom_top10.py\");p=\"DMC\";b=m[\"blend_properties\"](\"Pentane\",p);print(m[\"fom4\"](m[\"load_canonical_sigma\"]()[\"Pentane+\"+p][\"sigma\"],p,b));print(\"epsilon\",round(b[\"epsilon\"],2),\"mu\",round(b[\"mu_mPas\"],3))'",
    "receipt_paths": [
      "cooling-fluid-10/data/processed/corrected_fom_nist.json"
    ],
    "negative_control": "sigma=20.00 produces FoM4=3.24. Aromaticity correction leaves this separate dielectric calculation unchanged.",
    "basis": "literature-derived ideal mixing estimate, not measured epsilon or electrical safety. Source constants and molecular weights are in scripts/extend_fom_top10.py. Seven stored replicas do not all regenerate from committed raw data. Contact angle 26 degrees is a literature fallback.",
    "source": "gpt-6-astra read-only audit of this repository, 2026-09-07 (C1)"
  },
  {
    "id": "row-4",
    "claim": "MeOH+TriEG+h-BN highest modeled system-CHF flagship",
    "figure": "357.6 W/cm²; 90% interval 203.7–556.1; P(top-1) approximately 0.79",
    "reproduce_command": "PYTHONDONTWRITEBYTECODE=1 /opt/homebrew/bin/python3.11 -B cooling-fluid-10/scripts/phaseB/harden_survivors.py",
    "receipt_paths": [
      "cooling-fluid-10/data/processed/phaseB/hardened_system_ranking.json"
    ],
    "negative_control": "Zero-Marangoni versus normal same-stream control gives 111.5 versus 184.3 W/cm² for the Pentane+DMC reference.",
    "basis": "estimate: seeded Monte Carlo over literature properties, Zuber CHF and assumed enhancement multipliers. Exact stored P(top-1)=0.786 also regenerated. Nonflammability and actual CHF are unmeasured. The high-methanol 80:20 reference is not the 5:95 flagship composition.",
    "source": "gpt-6-astra read-only audit of this repository, 2026-09-07 (C1)"
  },
  {
    "id": "row-5",
    "claim": "HFO-1336mzz-Z+vinylene carbonate 70:30",
    "figure": "Modeled system CHF 228.8 W/cm²; claimed epsilon approximately 2.0 is rejected",
    "reproduce_command": "PYTHONDONTWRITEBYTECODE=1 /opt/homebrew/bin/python3.11 -B cooling-fluid-10/scripts/phaseB/harden_survivors.py",
    "receipt_paths": [
      "cooling-fluid-10/data/processed/phaseB/hardened_system_ranking.json",
      "cooling-fluid-10/data/processed/md_properties_raw.json"
    ],
    "negative_control": "VC aromaticity control changes its group assignment from 2.0 to 5.0; repaired blend lookup is 2.9.",
    "basis": "estimate: the command reproduces CHF, not a valid dielectric constant. Exact P(top-1)=0.165 regenerated. The repaired lookup conflicts with recorded MD epsilon=12.827; physical epsilon remains unresolved. Best, nonflammable and first-ever are not established.",
    "source": "gpt-6-astra read-only audit of this repository, 2026-09-07 (C1)"
  },
  {
    "id": "row-6",
    "claim": "Six-stage computational discovery engine with held-out RF R²>0.75",
    "figure": "Claimed R²>0.75 does not reproduce",
    "reproduce_command": null,
    "receipt_paths": [
      "cooling-fluid-10/docs/CROSS_VALIDATION_CONSOLIDATED_2026-04-19.md"
    ],
    "negative_control": "Missing-committed-input test control reproduces 15 failures; dictionary-anchor tests are not independent predictive validation.",
    "basis": "estimate: BEST_IDEAS.md and imported discovery-engine narrative. Committed validation documentation instead reports RF R²=0.421 and Chemprop retrain R²=0.279. Functioning individual stages do not establish the claimed end-to-end predictive performance.",
    "source": "gpt-6-astra read-only audit of this repository, 2026-09-07 (C1)"
  },
  {
    "id": "row-7",
    "claim": "Pentane+propylene carbonate 80:20",
    "figure": "Canonical FoM4 3.83×; delta-sigma 24.88 mN/m; epsilon estimate 11.31",
    "reproduce_command": "python3 -B -c 'import runpy;m=runpy.run_path(\"cooling-fluid-10/scripts/extend_fom_top10.py\");p=\"PC\";b=m[\"blend_properties\"](\"Pentane\",p);print(m[\"fom4\"](m[\"load_canonical_sigma\"]()[\"Pentane+\"+p][\"sigma\"],p,b));print(\"epsilon\",round(b[\"epsilon\"],2),\"mu\",round(b[\"mu_mPas\"],3))'",
    "receipt_paths": [
      "cooling-fluid-10/data/processed/corrected_fom_nist.json"
    ],
    "negative_control": "Shared FoM perturbation control; Hansen calculation is a miscibility-risk screen rather than proof of one phase.",
    "basis": "computational/literature estimate. Current pooled FoM is 3.70. FDA-GRAS wording does not establish safety or authorization of this coolant formulation and use. Direct-immersion suitability remains unverified.",
    "source": "gpt-6-astra read-only audit of this repository, 2026-09-07 (C1)"
  },
  {
    "id": "row-8",
    "claim": "Composition-drift sensing and autonomous replenishment family",
    "figure": "Internal dossier scores A-06=25; S-01=A-05=S-07=23",
    "reproduce_command": "PYTHONDONTWRITEBYTECODE=1 /opt/homebrew/bin/python3.11 -B -c 'import json;from pathlib import Path;score=lambda s:2*s[\"N\"]+sum(s[k] for k in (\"U\",\"C\",\"P\",\"F\"));print(\"CONTROL zero\",score(dict.fromkeys((\"N\",\"U\",\"C\",\"P\",\"F\"),0)));base=Path(\"cooling-fluid-10/data/processed/dossiers\")\nfor i in (\"A-06\",\"S-01\",\"A-05\",\"S-07\",\"C-15\"):\n p=base/(i+\".json\");d=json.loads(p.read_text());print(i,score(d[\"score\"]),str(p))'",
    "receipt_paths": [
      "cooling-fluid-10/data/processed/dossiers/A-06.json",
      "cooling-fluid-10/data/processed/dossiers/S-01.json",
      "cooling-fluid-10/data/processed/dossiers/A-05.json",
      "cooling-fluid-10/data/processed/dossiers/S-07.json"
    ],
    "negative_control": "Zero scoring inputs return zero. Closed-loop fractionation conservation control fails.",
    "basis": "estimate: weighted subjective dossier axes, not demonstrated control-system performance. FTO LOW and counsel_ready are stored internal labels. The existing fractionation simulation cannot support operating-stability claims.",
    "source": "gpt-6-astra read-only audit of this repository, 2026-09-07 (C1)"
  },
  {
    "id": "row-9",
    "claim": "Single-component methylcyclosiloxane direct-to-chip champion",
    "figure": "Claimed static epsilon approximately 2.4; recorded single-seed sigma 22.27 mN/m",
    "reproduce_command": null,
    "receipt_paths": [
      "cooling-fluid-10/data/processed/pfas_optimum/siloxane_md_sigma.json"
    ],
    "negative_control": "Upstream screen fails on missing sibling Pareto CSV; its siloxane static epsilon is a class constant.",
    "basis": "estimate: CLASS_STATIC_EPS in scripts/pfas_optimum/siloxane_marangoni_screen.py and docs/PFAS_FREE_COOLING_OPTIMUM.md. Raw candidate-specific dielectric and surface-tension regeneration are not established. The borrowed CoolProp 0.12% claim in imported/david/IDEA_RANKING.md does not validate this molecule.",
    "source": "gpt-6-astra read-only audit of this repository, 2026-09-07 (C1)"
  },
  {
    "id": "row-10",
    "claim": "Pentane+DMF pool-sigma riser",
    "figure": "BEST_IDEAS claims pooled FoM4 3.92×; current computation gives 3.81×",
    "reproduce_command": null,
    "receipt_paths": [
      "cooling-fluid-10/data/processed/multi_pair_uq_pool.json",
      "cooling-fluid-10/data/processed/corrected_fom_nist.json"
    ],
    "negative_control": "Constant-sigma temperature-fit control returns zero slope.",
    "basis": "estimate: the original 3.92×/n=5 claim is stale and has no current reproduction command. Current seven-member pool sigma=15.058 yields 3.81×. Separately, committed raw temperature-sweep XVGs reproduce slope=-0.1771395 and R²=0.965958 through scripts/propagate_g3_dmf_sigmaT.py.",
    "source": "gpt-6-astra read-only audit of this repository, 2026-09-07 (C1)"
  },
  {
    "id": "row-11",
    "claim": "Pressure-tuned composition",
    "figure": "Internal C-15 score 23/30; pure-fuel boiling-window estimates reproduce",
    "reproduce_command": "PYTHONDONTWRITEBYTECODE=1 /opt/homebrew/bin/python3.11 -B -c 'import json;from pathlib import Path;score=lambda s:2*s[\"N\"]+sum(s[k] for k in (\"U\",\"C\",\"P\",\"F\"));print(\"CONTROL zero\",score(dict.fromkeys((\"N\",\"U\",\"C\",\"P\",\"F\"),0)));base=Path(\"cooling-fluid-10/data/processed/dossiers\")\nfor i in (\"A-06\",\"S-01\",\"A-05\",\"S-07\",\"C-15\"):\n p=base/(i+\".json\");d=json.loads(p.read_text());print(i,score(d[\"score\"]),str(p))'",
    "receipt_paths": [
      "cooling-fluid-10/data/processed/dossiers/C-15.json",
      "cooling-fluid-10/docs/PRESSURE_TUNED_OPTIMA.md"
    ],
    "negative_control": "Pressure calculation returns its reference boiling point at one atmosphere.",
    "basis": "estimate: score arithmetic and pure-component pressure calculations. This does not regenerate mixture VLE, a composition optimum, or retargeting of any arbitrary blend.",
    "source": "gpt-6-astra read-only audit of this repository, 2026-09-07 (C1)"
  },
  {
    "id": "row-12",
    "claim": "Pentane+cyclohexanone 80:20 fallback",
    "figure": "Pooled FoM4 3.66×; epsilon estimate 3.96",
    "reproduce_command": "python3 -B -c 'import runpy;m=runpy.run_path(\"cooling-fluid-10/scripts/extend_fom_top10.py\");p=\"Cyclohexanone\";print(m[\"fom4\"](m[\"load_uq_pool\"]()[\"Pentane+\"+p][\"pool_mean_mNm\"],p,m[\"blend_properties\"](\"Pentane\",p)));print(\"epsilon\",round(m[\"blend_properties\"](\"Pentane\",p)[\"epsilon\"],2))'",
    "receipt_paths": [
      "cooling-fluid-10/data/processed/corrected_fom_nist.json",
      "cooling-fluid-10/data/processed/multi_pair_uq_pool.json"
    ],
    "negative_control": "Shared FoM perturbation control; independent Hansen arithmetic tests pass.",
    "basis": "computational/literature estimate. The separate Ra=7.64 claim belongs to cyclopentane+cyclohexanone, not pentane+cyclohexanone. Do not transfer its miscibility classification.",
    "source": "gpt-6-astra read-only audit of this repository, 2026-09-07 (C1)"
  },
  {
    "id": "row-13",
    "claim": "Nanoparticle and structured-surface cooling system",
    "figure": "No regenerated coolant-performance figure; BEST_IDEAS score 16 is subjective",
    "reproduce_command": null,
    "receipt_paths": [],
    "negative_control": "Empty enhancement list incorrectly selects the default enhanced stack.",
    "basis": "literature/estimate: enhancement_stack.py cites the foam, biphilic, nanoparticle and acoustic enhancement literature. Multipliers combine literature assumptions with tuned coupling; they are not measured FluxZero performance.",
    "source": "gpt-6-astra read-only audit of this repository, 2026-09-07 (C1)"
  },
  {
    "id": "row-14",
    "claim": "Microgravity or spacecraft self-pumping method",
    "figure": "No microgravity-specific performance figure; BEST_IDEAS score 12 is subjective",
    "reproduce_command": null,
    "receipt_paths": [],
    "negative_control": null,
    "basis": "estimate/hypothesis: BEST_IDEAS.md and cooling-fluid-10/scripts/lockspace/build_design_space.py, where the microgravity segment is unscored. No microgravity-specific validating simulation was established.",
    "source": "gpt-6-astra read-only audit of this repository, 2026-09-07 (C1)"
  },
  {
    "id": "row-15",
    "claim": "Methanol+triethylene glycol 80:20 indirect-loop reference",
    "figure": "FoM4 6.36× from a single-replica canonical sigma; epsilon estimate 32.18",
    "reproduce_command": "PYTHONDONTWRITEBYTECODE=1 /opt/homebrew/bin/python3.11 -B -c 'import runpy;m=runpy.run_path(\"cooling-fluid-10/scripts/extend_fom_top10.py\");f=\"MeOH\";p=\"TriEG\";b=m[\"blend_properties\"](f,p);print(m[\"fom4\"](m[\"load_canonical_sigma\"]()[f+\"+\"+p][\"sigma\"],p,b));print(\"CONTROL dsigma=0\",m[\"fom4\"](m[\"NIST_PURE\"][p][\"sigma_mNm\"],p,b));print(\"epsilon\",round(b[\"epsilon\"],2),\"mu\",round(b[\"mu_mPas\"],3))'",
    "receipt_paths": [
      "cooling-fluid-10/data/processed/corrected_fom_nist.json"
    ],
    "negative_control": "Setting the blend sigma to the pure-pump sigma (delta-sigma 0, no Marangoni gradient) still gives FoM4 5.51: the thermal term (18.2 times Novec) carries most of this figure.",
    "basis": "computational estimate: canonical single-replica sigma (sigma_n_replicas 1, no UQ pool) plus literature-property mixing. The epsilon estimate 32.18 is outside the immersion band, so this blend is an indirect-loop reference only. The high-methanol 80:20 reference is not the 5:95 flagship composition of row-4.",
    "source": "sites agent B, fork-4 fix-and-finish plan item 2d.4: command re-run in the idea 1 checkout 2026-09-17 (prints FoM4 6.36 and the control 5.51); added because the site printed 6.36× with no register row"
  }
]